What is chemical process calculation

The classical thermodynamics of simple systems

Applied Statistical Thermodynamics pp 1-21 | Cite as

Summary

In the applications of thermodynamics, material properties of fluids play a paramount role. The cycle processes of the energy conversion systems and the process energies converted in them are influenced to a large extent by state variables such as the volume, the enthalpy and the entropy of the working media. In technical thermodynamics [1–6] it is shown how these state variables are included in the process calculation. Process engineering systems are often based on phase and reaction equilibria in mixtures. In chemical thermodynamics, the relevant thermodynamic conditions for such states of equilibrium are generally formulated by thermodynamic functions, in particular the chemical potential [7–12]. All in all, these different aspects of the material behavior of fluid systems are covered by a closed and well-documented network of general equations: the equation framework of classical thermodynamics.

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Literature for Chapter 1

  1. Baehr, H. D .: Thermodynamics. Berlin: Springer-Verlag 1962CrossRefGoogle Scholar
  2. Schmidt, E .; Stephan, K .; Mayinger, F .: Technical Thermodynamics, Vol. 1. Berlin: Springer-Verlag 1975CrossRefGoogle Scholar
  3. Löffler, H. J .: Thermodynamik, Vol. 1. Berlin: Springer-Verlag 1969CrossRefGoogle Scholar
  4. Reynolds, W. C: Thermodynamics. New York: McGraw-Hill 1968Google Scholar
  5. Lee, J. F .; Sears, R.W .: Thermodynamics. Reading: Addison-Wesley 1963Google Scholar
  6. Kirillin, V. A .; Sycher, V. V .; Sheindlin, A. E .: Engineering thermodynamics. Moscow: Mir Publishers 1976Google Scholar
  7. Schmidt, E .; Stephan, K .; Mayinger, F .: Technical Thermodynamics, Vol. 2. Berlin: Springer-Verlag 1977CrossRefGoogle Scholar
  8. Löffler, H. J .: Thermodynamik, Vol. 2. Berlin: Springer-Verlag 1969CrossRefGoogle Scholar
  9. Denbigh, K .: The principles of chemical equilibrium. Oxford: Cambridge University Press 1971Google Scholar
  10. Bett, K. E .; Rowlinson, J. S .; Saville, G .: Thermodynamics for chemical engineers. London: The Athlone Press 1975Google Scholar
  11. Lewis, G. N .; Randall, M .; Pitzer, K. S .; Brewer, L .: Thermodynamics. New York: McGraw-Hill 1961Google Scholar
  12. Smith, J. M .; Van Ness, H. C: Introduction to chemical engineering thermodynamics. New York: McGraw-Hill 1975Google Scholar
  13. Callen, H. B .: Thermodynamics. New York: Wiley 1960zbMATHGoogle Scholar
  14. Bender, E .: The calculation of phase equilibria with the thermal equation of state - shown on the pure fluids argon, nitrogen, oxygen and their mixtures. Habilitation thesis, Ruhr University Bochum 1971Google Scholar
  15. Redlich, O .; Kwong, J. N. S .: Chem. Rev. 44 (1949) 233 CrossRefGoogle Scholar
  16. Ameling, W .; Siddiqi, M. A .; Lucas, K .: J. Chem. Eng. Data 28 (1983) 184 CrossRefGoogle Scholar
  17. Hanks, R. W .; Gupta, A. C; Christensen, J. J .: Ind. Eng. Chem. Fundam. 10 (1971) 504 CrossRefGoogle Scholar
  18. Siddiqi, M. A., Lucas, K .: Fluid Phase Equilibria 16 (1984) 87CrossRefGoogle Scholar
  19. Hildebrand, J. H., Prausnitz, J. M .; Scott, R. L .: Regular and Related Solutions. New York: Van Nostrand Reinhold 1970Google Scholar
  20. Gmehling, J .; Onken, U .: DECHEMA Chemistry Data Series. Vol. 1, part 1, 2 a and 2 b. Frankfurt: DECHEMA, 1977Google Scholar
  21. Paz-Andrade, M. J .: Int. Data Series A. A&M University Texas: Thermodynamic research center, 1973Google Scholar
  22. Diaz-Pena, M .; Menduina, C: J. Chem. Thermodyn. 6 (1974) 1097 Google Scholar
  23. Fredenslund, D .; Mollerup, J .: Faraday Trans. J. Chem. Soc. 70 (1974) 1653 CrossRefGoogle Scholar
  24. Wallis, K. P .; Chancy, P .; Zollweg, J. A .; Streett, W. B .: J. Chem. Thermodyn. 16 (1984) 811 CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1986

Authors and Affiliations

  1. 1. Department of ThermodynamicsUniversity of DuisburgDuisburg 1Germany